Lee, S., Kim, H.-S., Min, H.; Pyo, A. (2016)
Tetrahedron Letters, 57(2), 239-242
Benzoylacetonitrile were prepared through sequential carbonylation and decarboxylation. The palladium-catalyzed carbonylation of aryl iodides and methyl cyanoacetate using Mo(CO)6 as a carbon monoxide source afforded beta-keto cyanoesters, and then the subsequent reaction with Li/H2O produced the desired benzoylacetonitriles.
Subject headings: Benzoylacetonitrile; Palladium; Decarboxylation; Carbonylation; Aryl iodide
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Type: Journal Article
Serial number: 1495