Synthesis and complete assignment of the 1H and 13C NMR spectra of 6-substituted and 2,6-disubstituted pyridazin-3(2H)-ones

Author: Besada, P.; Costas, T.; Vila, N.; Chessa, C.; Teran, C.

Description: Several pyridazin-3(2H)-one derivatives were synthesized starting from alkyl furans using oxidation with singlet oxygen to give 4-methoxy or 4-hydroxybutenolides, key intermediates of the synthetic strategy followed. For all pyridazinones reported, a complete assignment of the (1)H and (13)C NMR spectra using one- and two-dimensional NMR spectroscopic methods, which included NOE, DEPT, COSY, HSQC and HMBC experiments, was accomplished. Correlations between the chemical shifts of the heterocyclic ring atoms and substituents at N-2 and C-6 were analyzed.

Subject headings: Synthesis; Pyridazin; Alkyl furans

Publication year: 2011

Journal or book title: Magnetic Resonance in Chemistry : MRC

Volume: 49

Issue: 7

Pages: 437-442

Find the full text : https://onlinelibrary.wiley.com/doi/abs/10.1002/mrc.2755

Find more like this one (cited by): https://scholar.google.com/scholar?cites=1590426210110143893&as_sdt=1000005&sciodt=0,16&hl=en

Type: Journal Article

Serial number: 34