Author: Cheek, G.T.; O’Grady, W.E.; El Abedin, S.Z.; Moustafa, E.M.; Endres, F.
Description: The electrochemical deposition of magnesium was investigated in the ionic liquids 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIm Formula ), 1-butyl-1-methylpyrrolidinium triflate (BMP TfO), and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfo nyl)amide (BMP Formula ). The electrochemical window of the imidazolium ionic liquid was insufficient for reduction of magnesium triflate, whereas the BMP systems can be used for the reduction of several magnesium salts. Studies of the reduction of other magnesium salts were carried out in nonaqueous solvents such as propylene carbonate for comparison with the work in ionic liquids. Stripping peaks for magnesium were observed in solutions of phenylmagnesium chloride in BMP Formula at elevated temperatures Formula .
Subject headings: electrochemistry; electrodeposition; magnesium; organic compounds
Publication year: 2008
Journal or book title: Journal of The Electrochemical Society
Volume: 155
Issue: 1
Pages: D91
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Type: Journal Article
Serial number: 1911