Author: Schwab, P.; France, M.B.; Ziller, J.W.; Grubbs, R.H.
Description: Substantially better initiators and therefore considerably more reactive than complexes of type A, the novel metathesis catalysts B are easily prepared by the reaction of [RuCl2(PPh3)3] with the appropriate diazoalkanes and subsequent phosphane exchange. While the PPh3 derivatives are excellent catalysts for living ROMP of norbornene, the complex with R = Cy, R′ = Ph is also a very efficient catalyst for the metathesis of acyclic alkenes.
Subject Headings: Catalysts-synthesis; Metathesis
Keywords: A Series of Well-Defined Metathesis Catalysts-Synthesis of[RuCl2(CHR’)(PR3)2] and Its Reactions
Publication year: 1995
Journal or book title: Angewandte Chemie International Edition in English
Volume: 34
Issue: 18
Pages: 2039-2041
Find the full text : https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.199520391
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Type: Journal Article
Serial number: 2560